Section: Module 1: Lesson 7: Free Energy | General Chemistry 2 | NextGenU.org

  • Student Learning Outcomes:
    Upon completion of this lesson, you will be able to:
    • Break down the concept of Gibbs free energy and describe its relation to spontaneity.
    • Calculate free energy change for a process using free energies of formation for its reactants and products.
    • Calculate free energy change for a process using enthalpies of formation and the entropies for its reactants and products.
    • Explain how temperature affects the spontaneity of some processes.
    • Relate standard free energy changes to equilibrium constants.
    Approximate time required for the readings for this lesson (at 144 words/minute): 2 hours and 58 minutes.

    Click here to start this lesson

    • Required Learning Resources and Activities
    • Read the contents under the headings "Learning Objectives" to "Key Concepts and Summary," and "Glossary." (16 minutes)

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    • General Instructions

      In this learning activity, you will reflect on all you have learned about thermochemistry and thermodynamics in order to perform calculations involving heat, enthalpy, entropy, or free energy and write a balanced chemical reaction. To successfully achieve this, you will need to review all the study materials for Module One.

      Step 1: Review

      Review the material based on the topics below.

      • Energy Basics
      • Enthalpy
      • The Second and Third Laws of Thermodynamics
      • Free Energy

      Step 2: Respond

      Read the scenario below, and using supporting data to back your arguments, prepare a 500-600 word written piece that answers all of the questions: 

      Case Scenario:

      An experiment was conducted to find the thermochemical and thermodynamic properties of a reaction. The reaction is between potassium chloride (KCl) and sulfuric acid (H2SO4). The reaction is as follows:

      In the experiment, the following values were obtained:

      • Mass of KCl = 2.4 g 
      • Temperature at start of reaction = 21°C
      • Temperature at the end of reaction = 28°C
      • Heat of fusion of KCl = 4.17 kJ/mol
      • Heat of reaction = -36.8 kJ
      • Entropy change of reaction = -21.2 J/K
      • Free energy of reaction = -30.2 kJ

      Questions:

      1. How much heat was released during the reaction?
      2. What is the enthalpy change of the reaction?
      3. What is the entropy change of the reaction at 25°C?
      4. What is the free energy change of the reaction at 25°C?
      5. How much energy is required to melt 1 mol of KCl?

      Step 3: Share 

      To share your work, click on the “Add a new discussion topic” button under this post and paste your work into the “Message” box. Make sure to reference others’ intellectual property when necessary. All references should follow 7th Edition APA formatting. For further instructions, see the resource on the Himmelfarb Health Sciences Library: APA citation resource (N.B.: references are excluded from word counts).

      Step 4: Interact 

      To complete the activity, evaluate and categorize the work from one of your peers based on items A - E of the rubric below. Provide a rationale for the grade you have provided, as well as comments or suggestions for improvement. To post a reply, click “Reply” on a particular discussion, write your feedback and then click on “Post to forum.” 

      You can use the list below as an example:

      Item A is  .…. because….  My suggestions for improvement are….
      Item B is  .…. because….  My suggestions for improvement are….
      Item C is  .…. because….  My suggestions for improvement are….
      Item D is  .…. because….  My suggestions for improvement are….
      Item E is  .…. because….  My suggestions for improvement are….

      OPTIONAL Step 5: Interact (10 minutes)

      If you would like to, you can reply to your peers' posts in a respectful and professional manner. Ensure that your post engages your peers' ideas by including a reflection on their comments, sharing ideas of other potential difficulties and parties involved, or asking thought-provoking questions. If a peer comments on your posting, please reply. To post a reply, click “Reply” on a particular discussion, write your feedback and then click on “Post to forum.”



    • To access the quiz, click on the name of the quiz provided above. On the following screen, click the attempt quiz button to view the case studies and respond to the questions.